Impact of ZnO Nanoparticle on the Structural and Optical Properties of Poly(vinyl alcohol) Film
DOI:
https://doi.org/10.23851/mjs.v33i4.1194Keywords:
Nanocomposite, Optical Properties, PVA/ZnO Nanoparticle, XRD, FTIR, UV-VisibleAbstract
Using the cast technique thin films of poly (vinyl alcohol) (PVA) containing varying amounts of Zinc Oxide ZnO nanoparticles (0.001, 0.002, 0.003, 0.004 and 0.005) g were formed. Physical properties excluded structural; (X-Ray Diffraction) (XRD), Fourier Transform Infrared (FT-IR) spectroscopy and UV-Visible spectroscopy. XRD results showed the amorphous structure of PVA film and Hexagonal crystalline structure of ZnONPs, PVA/ZnO nanocomposite appears as pattern of PVA films so the peaks of ZnO don't appear in it. FTIR spectra reveled ZnONPs doesn't have any influence on polymer structure. The effects of the ZnONPs on optical characteristics of PVA like the absorption spectrum, transmission spectrum, energy band gap, absorption coefficient, extinction coefficient, refractive index, real and imaginary parts of dielectric constant has been studied using UV-Vis spectroscopy. This study demonstrates that increasing the number of ZnONPs has an effect on all of these parameters.
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A.J.Kadham, D. Hassan, N. Mohammad, and A. Hashim, "Fabrication of (polymer blend-magnesium oxide) nanoparticle and studying their optical properties for optoelectronic applications," Bull. Electr. Eng. Informatics, vol. 7, no. 1, pp. 28-34, 2018.
H. Kasim and M. Yazici, "Electrical properties of graphene/natural rubber nanocomposites coated nylon 6.6 fabric under cyclic loading," Period. Polytech. Chem. Eng., vol. 63, no. 1, pp. 160-169, 2019.
W. Al-Taa'y, M. Abdul Nabi, R. M. Yusop, E. Yousif, B. M. Abdullah, J. Salimon, N. Salih and S. I. Zubairi, "Effect of nano ZnO on the optical properties of poly (vinyl chloride) films," International Journal of Polymer Science, vol. 2014, 2014.
T.Anantha kumar, S. Malathi, C. V. Mythili, and M. Jeyachandran, "Structural, Morphological and Optical Properties of Zinc Oxide Nanoparticles by Polymer Capping," Int. J. ChemTech Res., vol. 11, no. 8, pp. 48-57, 2018.
V.S. Sangawar and M. C. Golchha, "Evolution of the optical properties of Polystyrene thin films filled with Zinc Oxide nanoparticles," Int. J. Sci. Eng. Res., vol. 4, no. 6, pp. 2700-2705, 2013.
S. G. Dhole, S. A. Dake, T. A. Prajapati, and S. N. Helambe, "Effect of ZnO Filler on Structural and Optical Properties of Polyaniline-ZnO Nanocomposites," Procedia Manuf., vol. 20, pp. 127-134, 2018.
N. Bouropoulos, G. C. Psarras, N. Moustakas, A. Chrissanthopoulos, and S. Baskoutas, "Optical and dielectric properties of ZnO-PVA nanocomposites," Phys. Status Solidi Appl. Mater. Sci., vol. 205, no. 8, pp. 2033-2037, 2008.
K. H. H. Al-Attiyah, A. Hashim, and S. F. Obaid, "Fabrication of novel (carboxy methyl cellulose-polyvinylpyrrolidone-polyvinyl alcohol)/lead oxide nanoparticles: structural and optical properties for gamma rays shielding applications," I"Fabrication Nov. (Carboxy Methyl Cellul. Opt. Proper Gamma Rays Shield. Appl., vol. 23, no. 1, pp. 39-45, 2019.
A. Hadi and A. Hashim, "Development of a new humidity sensor based on (Carboxymethyl cellulose-starch) blend with copper oxide nanoparticles," Ukr. J. Phys., vol. 62, no. 12, pp. 1044-1049, 2017.
Shim and A. Hadi, "Novel lead oxide polymer nanocomposites for nuclear radiation shielding applications," Ukr. J. Phys., vol. 62, no. 11, pp. 978-983, 2017.
I. R. Agool, K. J. Kadhim, and A. Hashim, "Fabrication of new nanocomposites: (PVA-PEG-PVP) blend-zirconium oxide nanoparticles) for humidity sensors," Int. J. Plast. Technol., vol. 21, no. 2, pp. 397-403, 2017.
M. F. H. Al-kadhemy and Z. S. Rasheed, "Effect of Doping Ratio on optical properties of coumarin doped polystyrene films," vol. 3, no. 12, 2013.
Y. M. Jawad, M. F. H. Al-Kadhemy, and J. A. S. Salman, "Synthesis structural and optical properties of CMC/MgO nanocomposites," Mater. Sci. Forum, vol. 1039 MSF, no. July, pp. 104-114, 2021.
M. Abbas, M. Abdallah, and T. Alwan, "Optical characterization of Red Methyl Doped poly vinyl alcohol films," SOP Trans. Phys. Chem., vol. 1, no. 2, pp. 1-9, 2014.
N. J. Mohammed, Z. S. Rasheed, and A. S. Hassan, "Improvement Optical Properties of PVA/ TiO2 and PVA/ ZnO Nanocomposites," Al-Mustansiriyah J. Sci., vol. 29, no. 3, pp. 118-123, 2019.
S. G. Dhole, S. A. Dake, T. A. Prajapati, and S. N. Helambe, "Effect of ZnO Filler on Structural and Optical Properties of Polyaniline-ZnO Nanocomposites," Procedia Manuf., vol. 20, pp. 127-134, 2018.
A. S. Roy, S. Gupta, S. Sindhu, A. Parveen, and P. C. Ramamurthy, "Dielectric properties of novel PVA/ZnO hybrid nanocomposite films," Compos. Part B Eng., vol. 47, pp. 314-319, 2013.
A. Abdel-Galil, H. E. Ali, and M. R. Balboul, "Nano-ZnO Doping Induced Changes in Structure, Mechanical and Optical Properties of PVA Films," Arab J. Nucl. Sci. Appl., vol. 48, no. 2, pp. 77-89, 2015.
S. Maensiri, P. Laokul, and V. Promarak, "Synthesis and optical properties of nanocrystalline ZnO powders by a simple method using zinc acetate dihydrate and poly(vinyl pyrrolidone)," J. Cryst. Growth, vol. 289, no. 1, pp. 102-106, 2006.
K. S. Hemalatha, K. Rukmani, N. Suriyamurthy, and B. M. Nagabhushana, "Synthesis characterization and optical properties of hybrid PVA-ZnO nanocomposite: A composition dependent study," Mater. Res. Bull., vol. 51, pp. 438-446, 2014.
S. Pervaiz, N. Kanwal, S. A. Hussain, M. Saleem, and I. A. Khan, "Study of structural, optical and dielectric properties of ZnO/PVDF-based flexible sheets," J. Polym. Res., vol. 28, no. 8, pp. 1-13, 202.
T. S. Soliman, A. M. Rashad, I. A. Ali, S. I. Khater, and S. I. Elkalashy, "Investigation of Linear Optical Parameters and Dielectric Properties of Polyvinyl Alcohol/ZnO Nanocomposite Films," Phys. Status Solidi Appl. Mater. Sci., vol. 217, no. 19, pp. 1-8, 2020.
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