Impact of ZnO Nanoparticle on the Structural and Optical Properties of Poly(vinyl alcohol) Film

Authors

  • Ghadeer Abdul Hadi Abdul Jabbar Department of Physics, College of Science, Mustansiriyah University, Baghdad, IRAQ.
  • Asrar Abdulmunem Saeed Department of Physics, College of Science, Mustansiriyah University, Baghdad, IRAQ. https://orcid.org/0000-0003-4677-7598
  • Mahasin F. Hadi AL-Kadhemy Department of Physics, College of Science, Mustansiriyah University, Baghdad, IRAQ. https://orcid.org/0000-0002-7167-0218

DOI:

https://doi.org/10.23851/mjs.v33i4.1194

Keywords:

Nanocomposite, Optical Properties, PVA/ZnO Nanoparticle, XRD, FTIR, UV-Visible

Abstract

Using the cast technique thin films of poly (vinyl alcohol) (PVA) containing varying amounts of Zinc Oxide ZnO nanoparticles (0.001, 0.002, 0.003, 0.004 and 0.005) g were formed. Physical properties excluded structural; (X-Ray Diffraction) (XRD), Fourier Transform Infrared (FT-IR) spectroscopy and UV-Visible spectroscopy. XRD results showed the amorphous structure of PVA film and Hexagonal crystalline structure of ZnONPs, PVA/ZnO nanocomposite appears as pattern of PVA films so the peaks of ZnO don't appear in it. FTIR spectra reveled ZnONPs doesn't have any influence on polymer structure. The effects of the ZnONPs on optical characteristics of PVA like the absorption spectrum, transmission spectrum, energy band gap, absorption coefficient, extinction coefficient, refractive index, real and imaginary parts of dielectric constant has been studied using UV-Vis spectroscopy. This study demonstrates that increasing the number of ZnONPs has an effect on all of these parameters.

References

A.J.Kadham, D. Hassan, N. Mohammad, and A. Hashim, "Fabrication of (polymer blend-magnesium oxide) nanoparticle and studying their optical properties for optoelectronic applications," Bull. Electr. Eng. Informatics, vol. 7, no. 1, pp. 28-34, 2018.

CrossRef DOI: https://doi.org/10.11591/eei.v7i1.839

H. Kasim and M. Yazici, "Electrical properties of graphene/natural rubber nanocomposites coated nylon 6.6 fabric under cyclic loading," Period. Polytech. Chem. Eng., vol. 63, no. 1, pp. 160-169, 2019.

CrossRef DOI: https://doi.org/10.3311/PPch.12122

W. Al-Taa'y, M. Abdul Nabi, R. M. Yusop, E. Yousif, B. M. Abdullah, J. Salimon, N. Salih and S. I. Zubairi, "Effect of nano ZnO on the optical properties of poly (vinyl chloride) films," International Journal of Polymer Science, vol. 2014, 2014.

CrossRef DOI: https://doi.org/10.1155/2014/697809

T.Anantha kumar, S. Malathi, C. V. Mythili, and M. Jeyachandran, "Structural, Morphological and Optical Properties of Zinc Oxide Nanoparticles by Polymer Capping," Int. J. ChemTech Res., vol. 11, no. 8, pp. 48-57, 2018.

CrossRef DOI: https://doi.org/10.20902/IJCTR.2018.110805

V.S. Sangawar and M. C. Golchha, "Evolution of the optical properties of Polystyrene thin films filled with Zinc Oxide nanoparticles," Int. J. Sci. Eng. Res., vol. 4, no. 6, pp. 2700-2705, 2013.

S. G. Dhole, S. A. Dake, T. A. Prajapati, and S. N. Helambe, "Effect of ZnO Filler on Structural and Optical Properties of Polyaniline-ZnO Nanocomposites," Procedia Manuf., vol. 20, pp. 127-134, 2018.

CrossRef

N. Bouropoulos, G. C. Psarras, N. Moustakas, A. Chrissanthopoulos, and S. Baskoutas, "Optical and dielectric properties of ZnO-PVA nanocomposites," Phys. Status Solidi Appl. Mater. Sci., vol. 205, no. 8, pp. 2033-2037, 2008.

CrossRef DOI: https://doi.org/10.1002/pssa.200778863

K. H. H. Al-Attiyah, A. Hashim, and S. F. Obaid, "Fabrication of novel (carboxy methyl cellulose-polyvinylpyrrolidone-polyvinyl alcohol)/lead oxide nanoparticles: structural and optical properties for gamma rays shielding applications," I"Fabrication Nov. (Carboxy Methyl Cellul. Opt. Proper Gamma Rays Shield. Appl., vol. 23, no. 1, pp. 39-45, 2019.

CrossRef DOI: https://doi.org/10.1007/s12588-019-09228-5

A. Hadi and A. Hashim, "Development of a new humidity sensor based on (Carboxymethyl cellulose-starch) blend with copper oxide nanoparticles," Ukr. J. Phys., vol. 62, no. 12, pp. 1044-1049, 2017.

CrossRef DOI: https://doi.org/10.15407/ujpe62.12.1044

Shim and A. Hadi, "Novel lead oxide polymer nanocomposites for nuclear radiation shielding applications," Ukr. J. Phys., vol. 62, no. 11, pp. 978-983, 2017.

CrossRef DOI: https://doi.org/10.15407/ujpe62.11.0978

I. R. Agool, K. J. Kadhim, and A. Hashim, "Fabrication of new nanocomposites: (PVA-PEG-PVP) blend-zirconium oxide nanoparticles) for humidity sensors," Int. J. Plast. Technol., vol. 21, no. 2, pp. 397-403, 2017.

CrossRef DOI: https://doi.org/10.1007/s12588-017-9192-5

M. F. H. Al-kadhemy and Z. S. Rasheed, "Effect of Doping Ratio on optical properties of coumarin doped polystyrene films," vol. 3, no. 12, 2013.

Y. M. Jawad, M. F. H. Al-Kadhemy, and J. A. S. Salman, "Synthesis structural and optical properties of CMC/MgO nanocomposites," Mater. Sci. Forum, vol. 1039 MSF, no. July, pp. 104-114, 2021.

CrossRef DOI: https://doi.org/10.4028/www.scientific.net/MSF.1039.104

M. Abbas, M. Abdallah, and T. Alwan, "Optical characterization of Red Methyl Doped poly vinyl alcohol films," SOP Trans. Phys. Chem., vol. 1, no. 2, pp. 1-9, 2014.

CrossRef DOI: https://doi.org/10.15764/PCHE.2014.02001

N. J. Mohammed, Z. S. Rasheed, and A. S. Hassan, "Improvement Optical Properties of PVA/ TiO2 and PVA/ ZnO Nanocomposites," Al-Mustansiriyah J. Sci., vol. 29, no. 3, pp. 118-123, 2019.

CrossRef DOI: https://doi.org/10.23851/mjs.v29i3.629

S. G. Dhole, S. A. Dake, T. A. Prajapati, and S. N. Helambe, "Effect of ZnO Filler on Structural and Optical Properties of Polyaniline-ZnO Nanocomposites," Procedia Manuf., vol. 20, pp. 127-134, 2018.

CrossRef DOI: https://doi.org/10.1016/j.promfg.2018.02.018

A. S. Roy, S. Gupta, S. Sindhu, A. Parveen, and P. C. Ramamurthy, "Dielectric properties of novel PVA/ZnO hybrid nanocomposite films," Compos. Part B Eng., vol. 47, pp. 314-319, 2013.

CrossRef DOI: https://doi.org/10.1016/j.compositesb.2012.10.029

A. Abdel-Galil, H. E. Ali, and M. R. Balboul, "Nano-ZnO Doping Induced Changes in Structure, Mechanical and Optical Properties of PVA Films," Arab J. Nucl. Sci. Appl., vol. 48, no. 2, pp. 77-89, 2015.

S. Maensiri, P. Laokul, and V. Promarak, "Synthesis and optical properties of nanocrystalline ZnO powders by a simple method using zinc acetate dihydrate and poly(vinyl pyrrolidone)," J. Cryst. Growth, vol. 289, no. 1, pp. 102-106, 2006.

CrossRef DOI: https://doi.org/10.1016/j.jcrysgro.2005.10.145

K. S. Hemalatha, K. Rukmani, N. Suriyamurthy, and B. M. Nagabhushana, "Synthesis characterization and optical properties of hybrid PVA-ZnO nanocomposite: A composition dependent study," Mater. Res. Bull., vol. 51, pp. 438-446, 2014.

CrossRef DOI: https://doi.org/10.1016/j.materresbull.2013.12.055

S. Pervaiz, N. Kanwal, S. A. Hussain, M. Saleem, and I. A. Khan, "Study of structural, optical and dielectric properties of ZnO/PVDF-based flexible sheets," J. Polym. Res., vol. 28, no. 8, pp. 1-13, 202.

CrossRef DOI: https://doi.org/10.1007/s10965-021-02640-9

T. S. Soliman, A. M. Rashad, I. A. Ali, S. I. Khater, and S. I. Elkalashy, "Investigation of Linear Optical Parameters and Dielectric Properties of Polyvinyl Alcohol/ZnO Nanocomposite Films," Phys. Status Solidi Appl. Mater. Sci., vol. 217, no. 19, pp. 1-8, 2020.

CrossRef DOI: https://doi.org/10.1002/pssa.202000321

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Published

30-12-2022

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Section

Physical Sciences

How to Cite

[1]
G. A. H. Abdul Jabbar, A. A. . . Saeed, and M. F. H. AL-Kadhemy, “Impact of ZnO Nanoparticle on the Structural and Optical Properties of Poly(vinyl alcohol) Film”, Al-Mustansiriyah Journal of Science, vol. 33, no. 4, pp. 153–161, Dec. 2022, doi: 10.23851/mjs.v33i4.1194.

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