Synthesis and Characterization of Graphene Oxide for Efficient Adsorptive Removal of Hymexazol Pesticide from Aqueous Solutions: Thermodynamic, Kinetic, and Isotherm Studies

Authors

DOI:

https://doi.org/10.23851/mjs.v35i2.1493

Keywords:

Adsorption, Graphene Oxide, Hymexazol, Modified Hummer Method, Nanomaterial

Abstract

Background: Nanomaterials play a significant role in the field of water treatment due to their environment-friendly and appealing physical and chemical characteristics. Objective: The purpose of this research is to evaluate whether graphene oxide adsorbents can effectively remove hymexazol pesticide from an aqueous solution. Methods: Graphene oxide (GO) was prepared by the modified Hummer method, and it was characterized by a number characterization techniques, including XRD, Raman spectroscopy, FE-SEM, TEM, and EDX. Furthermore, the performances of the GO adsorbents for the removal of hymexazol from aqueous solution were investigated. The effect of contact time, GO dosage, initial hymexazol concentration, and temperature was carefully studied. Results: The kinetic experimental data were best described by the pseudo-second-order kinetic model. The equilibrium data were well fitted by the Freundlich and Langmuir isotherm models. The kinetic experimental data were best described by the pseudo-second-order kinetic model. And through the thermodynamic studies, it was found that the adsorption process of hymexazol pesticide is endothermic and spontaneous, in addition to the occurrence of adsorption and absorption together. Conclusions: The findings of the adsorption process demonstrated that graphene oxide is an extremely efficient adsorbent material for pesticide adsorption, owing to its large surface area and the presence of oxygen-rich groups on its surface.

Downloads

Download data is not yet available.

References

A. M. Rheima, "Zinc oxide nanotubes: Synthesis, diagnosis and study the adsorption ability of mercury and lead ions from their aqueous solutions," Journal of Advanced Sciences and Nanotechnology, pp. 20-36, 2022.

CrossRef

A. R. Laftah, "New synthesis of bao nanoparticles using the uv-irradiation technique for removal cibacron blue dye from their aqueous solution," Egyptian Journal of Chemistry, p. 13, 2022.

CrossRef

B. E. Jasim, "Nickel oxide nanofibers manufactured via sol-gel method: Synthesis, characterization and use it as a photo-anode in the dye sensitized solar cell," Digest Journal of Nanomaterials & Biostructures (DJNB), 2022.

CrossRef

A. Rheima, "Novel method to synthesis nickel oxide nanoparticles for antibacterial activity," Iranian Journal of Physics Research, pp. 51-55, 2020.

A. Awasthi, "Clay nano-adsorbent: Structures, applications and mechanism for water treatment," SN Applied Sciences, vol. 1, pp. 1-12, 2019.

CrossRef

S. Husain, "Emerging trends in advanced translational applications of silver nanoparticles: A progressing dawn of nanotechnology," Journal of Functional Biomaterials, vol. 14, no. 1, p. 47, 2023.

CrossRef | PubMed

G. Vijayakumar, "Detection of food toxins, pathogens, and microorganisms using nanotechnology-based sensors," in Nanotechnology Applications for Food Safety and Quality Monitoring. 2023, pp. 155-170.

CrossRef

S. Malik, "Nanotechnology: A revolution in modern industry," Molecules, vol. 28, no. 2, p. 661, 2023.

CrossRef | PubMed

L. Inbathamizh, "Nanotechnology: Ethical impacts, health issues, and safety issues," in Modern Nanotechnology: Volume 2: Green Synthesis, Sustainable Energy and Impacts. 2023, pp. 455-477.

CrossRef

P. Biswas, "Advanced implications of nanotechnology in disease control and environmental perspectives," Biomedicine & Pharmacotherapy, vol. 158, p. 114 172, 2023.

CrossRef | PubMed

K. Neeti, "The role of green nanomaterials as effective adsorbents and applications in wastewater treatment,"Materials Today: Proceedings, vol. 77, pp. 269-272, 2023.

CrossRef

R. Kumar, Advanced Functional Nanoparticles" Boon or Bane" for Environment Remediation Applications: Combating Environmental Issues. 2023.

CrossRef

H. Hu, "Physicochemical technologies for hrps and risk control," in 2020, pp. 169-207.

CrossRef

F. Tunioli, "Adsorption of emerging contaminants by graphene related materials and their alginate composite hydrogels," Journal of Environmental Chemical Engineering, p. 109 566, 2023.

CrossRef

U. Rajaji, "A sonochemical synthesis of srtio3 supported n-doped graphene oxide as a highly efficient electrocatalyst for electrochemical reduction of a chemotherapeutic drug," Ultrasonics Sonochemistry, p. 106 293, 2023.

CrossRef | PubMed

L. Liang, "In situ synthesis of a go/cofs composite with enhanced adsorption performance for organic pollutants in water," Environmental Science: Nano, pp. 554-567, 2022.

CrossRef

H. Jafarian, "Synthesis of heterogeneous metal organic framework-graphene oxide nanocomposite membranes for water treatment," Chemical Engineering Journal, p. 140 851, 2023.

CrossRef

V. Palmieri, "Graphene oxide-mediated copper reduction allows comparative evaluation of oxygenated reactive residues exposure on the materials surface in a simple one-step method," Applied Surface Science, p. 156 312, 2023.

CrossRef

F. Jia, "Advances in graphene oxide membranes for water treatment," Nano Research, pp. 6636-6654, 2022.

CrossRef

Y. Li, "Tailoring the physicochemical and geometric properties of two-dimensional graphene membranes for aqueous separation," Desalination, vol. 530, p. 115 621, 2022.

CrossRef

Y. Rezaeipour, "The anticancer properties of metal-organic frameworks and their heterogeneous nanocomposites,"Biomaterials Advances, p. 213 013, 2022.

CrossRef | PubMed

K. Chen, "Graphene oxide bulk material reinforced by heterophase platelets with multiscale interface crosslinking," Nature Materials, pp. 1121-1129, 2022.

CrossRef | PubMed

D. J. Joshi, "Surface modifications and analytical applications of graphene oxide: A review," TrAC Trends in Analytical Chemistry, p. 116 448, 2021.

CrossRef

Y. A. B. Neolaka, "The adsorption of cr (vi) from water samples using graphene oxide-magnetic (go-fe3o4) synthesized from natural cellulose-based graphite (kusambi wood or schleichera oleosa): Study of kinetics, isotherms and thermodynamics," Journal of Materials Research and Technology, vol. 9, no. 3, pp. 6544-6556, 2020.

CrossRef

R. H. Krishna, "Carbon nanotubes and graphene-based materials for adsorptive removal of metal ions-a review on surface functionalization and related adsorption mechanism," Applied Surface Science Advances, vol. 13, p. 100 431, 2023.

CrossRef

B. F. M. L. Gomes, "Synthesis and application of graphene oxide as a nanoadsorbent to remove cd (ii) and pb (ii) from water: Adsorption equilibrium, kinetics, and regeneration," Environmental Science and Pollution Research, pp. 17 358-17 372, 2022.

N. Jahan, "A comparative study on sorption behavior of graphene oxide and reduced graphene oxide towards methylene blue," Case Studies in Chemical and Environmental Engineering, p. 100 239,

R. G. Abaszade, "Synthesis and analysis of flakes graphene oxide," Journal of Optoelectronic and Biomedical Materials, pp. 107-114, 2022.

CrossRef

A. Verma, "Application of wastewater in agriculture: Benefits and detriments," in River Conservation and Water Resource Management. 2023, pp. 53-75.

CrossRef

I. El-Nahhal, "Pesticide residues in drinking water, their potential risk to human health and removal options,"Journal of Environmental Management, p. 113 611, 2021.

CrossRef | PubMed

M. S. Nazir, "Remediation of pesticide in water," in Sustainable Agriculture Reviews 47. 2021, pp. 271-307.

CrossRef

N. Dhankhar, "Impact of increasing pesticides and fertilizers on human health: A review," Materials Today: Proceedings, 2023.

CrossRef

C. Panis, "Widespread pesticide contamination of drinking water and impact on cancer risk in brazil," Environment International, p. 107 321, 2022.

CrossRef | PubMed

S. Boulkhessaim, "Emerging trends in the remediation of persistent organic pollutants using nanomaterials and related processes: A review," Nanomaterials, p. 2148, 2022.

CrossRef | PubMed

S. Singh, "Pesticides in water," in Handbook of water purity and quality. 2021, pp. 231-253.

CrossRef

A. Yousfi, "Bifenthrine & hymexazol toxic effects on helix aspersa and the evaluation of the protective effect of orange essential oils," Annals of the Romanian Society for Cell Biology, vol. 26, no. 01, pp. 3270-3284, 2022.

E. I. Hassanen, "A comprehensive study on the mechanistic way of hexaflumuron and hymexazol induced neurobehavioral toxicity in rats," Neurochemical Research, vol. 47, no. 10, pp. 3051-3062, 2022.

CrossRef | PubMed

N. H. Hassan, "The potential mechanism underlying the hepatorenal toxicity induced by hymexazol in rats and the role of nf‐ffb signaling pathway," Journal of Biochemical and Molecular Toxicology, e23304, 2023. .

CrossRef | PubMed

F. Mohammed, "Effective removal of hymexazol pesticide from polluted water using cadmium oxide nanoparticles prepared by photolysis methods: Thermodynamic, kinetic, and isothermal studies," Journal of Wildlife and Biodiversity, vol. 7, no. Special Issue, pp. 586-600, 2023.

P. Chen, "Selective removal of heavy metals by zr-based mofs in wastewater: New acid and amino functionalization strategy," Journal of Environmental Sciences, pp. 268-280, 2023.

CrossRef | PubMed

M. A. Báez-Sañudo, "Assessment of residuality of hymexazol in strawberry (fragaria× ananassa) crop by a modified quechers method and liquid chromatography tandem-mass spectrometry," Agronomy, vol. 12, no. 12, p. 3110, 2022.

CrossRef

K. D. Khalil, "Fabrication of dye-sensitized solar cells and synthesis of cunio2 nanostructures using a photoirradiation technique," Polymers, p. 2827, 2022.

X. Xu, "Biosynthesis of sorafenib coated graphene nanosheets for the treatment of gastric cancer in patients in nursing care," Journal of Photochemistry and Photobiology B: Biology, vol. 191, pp. 1-5, 2019.

CrossRef | PubMed

Z. Li, "Raman spectroscopy of carbon materials and their composites: Graphene, nanotubes and fibres," Progress in Materials Science, p. 101 089, 2023.

CrossRef

S.-h. Urashima, "Non-destructive estimation of the cation composition of natural carbonates by micro-raman spectroscopy," Analytica Chimica Acta, p. 340 798, 2023.

CrossRef | PubMed

S. Farah, "Comparison of thermally and chemically reduced graphene oxides by thermal analysis and raman spectroscopy," Journal of Thermal Analysis and Calorimetry, pp. 331-337, 2020.

CrossRef

S. Bidmeshkipour, "Graphene nanopores in broadband wide-angle optical cavity resonance absorbers," Surfaces and Interfaces, p. 101 956, 2022.

CrossRef

T. Bandara, "An electrochemical route to exfoliate vein graphite into graphene with black tea," Materials Chemistry and Physics, p. 126 450, 2022.

CrossRef

E. Jaafar, "Study on morphological, optical and electrical properties of graphene oxide (go) and reduced graphene oxide (rgo)," in Materials Science Forum. 2018.

CrossRef

N. S. Suhaimin, "The evolution of oxygen-functional groups of graphene oxide as a function of oxidation degree,"Materials Chemistry and Physics, p. 125 629, 2022.

CrossRef

X. Wang, "Quantifying orientation and curvature in hrtem lattice fringe micrographs of naturally thermally altered coals: New insights from a structural evolution perspective," Fuel, p. 122 180, 2022.

CrossRef

S. Deng, "In vivo toxicity assessment of four types of graphene quantum dots (gqds) using mrna sequencing," Toxicology Letters, pp. 55-66, 2022.

CrossRef | PubMed

Y. E. Hassen, "Dodonaea angustifolia extract-assisted green synthesis of the cu2o/al2o3 nanocomposite for adsorption of cd(ii) from water," ACS Omega, vol. 8, no. 19, pp. 17 209-17 219, 2023. doi: 10.1021/acsomega.3c01609.

CrossRef | PubMed

P. Sikarwar, "Adsorptive denitrogenation of indole from model fuel oil over co-mac: Adsorption mechanisms and competitive adsorption," Journal of the Indian Chemical Society, p. 100 801, 2023.

CrossRef

X. Qi, "Recent advances in polysaccharide-based adsorbents for wastewater treatment," Journal of Cleaner Production, p. 128 221, 2021.

CrossRef

T. A. Aragaw, "A comparative study of acidic, basic, and reactive dyes adsorption from aqueous solution onto kaolin adsorbent: Effect of operating parameters, isotherms, kinetics, and thermodynamics," Emerging Contaminants, pp. 59-74, 2022.

CrossRef

Z. R. Zair, "Optimization, equilibrium, kinetics and thermodynamic study of congo red dye adsorption from aqueous solutions using iraqi porcelanite rocks," Heat and Mass Transfer, vol. 58, no. 8, pp. 1393-1410, 2022.

CrossRef

N. Ahadi, "Facile synthesis of hierarchically structured mil-53 (al) with superior properties using an environmentallyfriendly ultrasonic method for separating lead ions from aqueous solutions," Scientific Reports, pp. 1-17, 2022.

CrossRef | PubMed

H. S. Alhares, "Sunflower husks coated with copper oxide nanoparticles for reactive blue 49 and reactive red 195 removals: Adsorption mechanisms, thermodynamic, kinetic, and isotherm studies," Water, Air, & Soil Pollution, vol. 1, no. 35, p. 234, 2023.

CrossRef

J. N. Wekoye, "Kinetic and equilibrium studies of congo red dye adsorption on cabbage waste powder," Environmental Chemistry and Ecotoxicology, vol. 2, pp. 24-31, 2020.

CrossRef

M. A. Al-Ghouti, "Guidelines for the use and interpretation of adsorption isotherm models: A review," Journal of hazardous materials, p. 122 383, 2020.

CrossRef | PubMed

M. A. Al-Ghouti, "Mechanistic understanding of the adsorption and thermodynamic aspects of cationic methylene blue dye onto cellulosic olive stones biomass from wastewater," Scientific Reports, vol. 10, no. 1, pp. 1-18, 2020.

CrossRef | PubMed

H. Patel, "Comparison of batch and fixed bed column adsorption: A critical review," International Journal of Environmental Science and Technology, pp. 10 409-10 426, 2022.

C.-K. How, "Adsorption properties of ff-carotene on mesoporous carbon-coated honeycomb monolith: Kinetics, thermodynamics, and regeneration studies," Korean Journal of Chemical Engineering, vol. 39, no. 11, pp. 3109-3120, 2022.

CrossRef

I. Maamoun, "Insights into kinetics, isotherms and thermodynamics of phosphorus sorption onto nanoscale zerovalent iron," Journal of Molecular Liquids, vol. 238, p. 115 402, 2021.

CrossRef

Downloads

Key Dates

Received

19-09-2023

Revised

18-12-2023

Accepted

02-01-2024

Published

30-06-2024

Data Availability Statement

None

Issue

Section

Original Article

How to Cite

[1]
F. M. Abdullah, A. H. Ismail, and A. M. . Rheima, “Synthesis and Characterization of Graphene Oxide for Efficient Adsorptive Removal of Hymexazol Pesticide from Aqueous Solutions: Thermodynamic, Kinetic, and Isotherm Studies”, Al-Mustansiriyah J. Sci., vol. 35, no. 2, pp. 70–82, Jun. 2024, doi: 10.23851/mjs.v35i2.1493.

Similar Articles

1-10 of 205

You may also start an advanced similarity search for this article.