Investigate Physical Properties and Intensity of Sun Light Transmitted through Safranin/PMMA Films

Authors

  • Noor Alzhraa H. Darweesh Department of Physics College of Science, Mustansiriyah University, Baghdad, IRAQ.
  • Mahasin F. Hadi Department of Physics College of Science, Mustansiriyah University, Baghdad, IRAQ.
  • Asrar Abdulmunem Saeed Department of Physics College of Science, Mustansiriyah University, Baghdad, IRAQ.

DOI:

https://doi.org/10.23851/mjs.v33i2.1101

Keywords:

Safranin Dye, Polymethylmethacrylate, Physical Properties, Sun Light.

Abstract

To investigate the effect of safranin additions on the optical properties of PMMA hosts, films of pure and doped polymethylmethacrylate (PMMA) with various volumes of safranin (S) dye solution (6, 12, 18, 24, 30, and 35 ml) were equipped via the solution-casting method at room temperature. For an aim of assessing the kind of transition that was established to be indirect transition, these films were described using the method of UV/VIS. It showed absorption characteristic peak at 530 nm which increased with dye concentration until 24ml after that absorbance will decrease for (30 and 36) ml. The optical energy gap of polymethylmethacrylate (PMMA) was (5.0 eV) and after doping PMMA polymer with safranin dye, the energy gap value of the PMMA films raised as the volume ratio of Safranin solution raised but for volume doping 24ml of safranin solution, the energy gap reduced. The intensity of solar radiation was measured for pure PMMA and safranin /PMMA films, for four consecutive days from 7 A.M. to 5 P.M. (17 hr.), at a rate one hour. It can be concluded that the ratio of the transmitted radiation intensity to the intensity of the sun's radiation for all films is equal for every hour and for all days.

References

W. D. Callister, Materials Science and Engineering, John Wiley & Sons, New York, 2007.

C. Espejo, A. Arribas, F. Monzo', P. P. Dı'ez, Nano composite films with enhanced radiometric properties for greenhouse covering applications, Journal of Plastic Film & Sheeting,28(4), (2012),336-350.

CrossRef

N. Hendawy, A. Bakr, T. Y. Elrasasi, "Optimization of the optical properties of Safranine O -Polycarbonate composites for Algae Greenhouse Applications", Journal of Basic and Environmental Sciences, 4, 362-369, (2017).

T. K. Hamad, M. T. Abdul nabi, W. A. Musa, "The optical properties of Poly methyl methacrylate (PMMA) polymers doped by Potassium Iodide with different thickness", Baghdad Science Journal, 8(2), 538-542, (2011).

CrossRef

D. E. Al- Mammar "Decolorization of the aqueous Safranin O dye solution using Thuja orientalis as biosorbent", Iraqi Journal of Science, 55(3A), 886-898,(2014).

K. O. Adebowale, B. I. Olu-Owolabi, E.C. Chigbundu, "Removal of Safranin-O from Aqueous Solution by Adsorption onto Kaolinite Clay", Journal of Encapsulation and Adsorption Sciences,4, 89-104, (2014).

CrossRef

M. Serrano, J. C. Moreno, "Spectral transmission of solar radiation by plastic and glass materials", J. of Photochemistry and Photobiology B: Biology, 208, 111894, (2020).

CrossRef | PubMed

F. Padera, "Measuring Light Transmittance and UVA and UVB of Transparent Materials using the PerkinElmer LAMBDA 35", Perkin Elmer, INC, (2013).

Z.M. Elimat, A.M. Zihlif & M. Avella, "Thermal and optical properties of poly (methyl methacrylate)/calcium carbonate nanocomposite", Journal of Experimental Nanoscience, 3(4), 259-269, (2008).

CrossRef

G. Balaji, R.K. Rekha and A. Ramalingam, "Nonlinear Characterization of Safranin O Dye for Application in Optical Limiting", Acta Physica Polonica A, 119(3), 359-363, (2011).

CrossRef

M. F H. Al-Kadhemy, W. H. Abbas, "Absorption spectrum of Crystal Violet in Chloroform solution and doped PMMA thin films", Atti Della Fondazione Giorgio Ronchi, 3, 359-366, (2012).

H. K. Ibrahim, "The surface and volume energy loss of Safranin O thin film prepared by spin coating method", Advances in Physics Theories and Applications, 53, 63-73, (2016).

T. Roychowdhury, Dh. Shah, J. N. Hilfiker, and M. R. Linford, "Polymethyl methacrylate: Optical properties from 191 to 1688 nm (0.735-6.491 eV) by spectroscopic ellipsometry", Surface Science Spectra 27, 024201 (2020).

CrossRef

M.N.B. -S. Valeur, "Molecular Fluorescence, Principle and applications", 2nd ed., John Wiley& Sons, (2013).

L.D. Field, S. Sternhell and J. R. Kalman, "Organic Structures from Spectra", John Wiley and Sons, (2008).

M. FOX, "Optical Properties of Solids", Oxford University press, (2007).

C. Klingshirn, "Semiconductor Optics", Verlag Berlin Heidelberg, New York, (1997).

M. F. H. Al-Kadhemy, R. A. Al-Mousawi, F. J. Kadhum, "Effects of Adding Coumarin Dye on Physical Properties of Blend (PC-PS) Film", Iraqi Journal of Science 61(7), 1633-1644, (2020).

M. F. H. Al-Kadhemy, A.A. Saeed, R. I. Khaleel & F. J. K. Al- Nuaimi, "Effect of gamma ray on optical characteristics of (PMMA/PS) polymer blends", Journal of Theoretical and Applied Physics,11(3), 201-207, (2017).

CrossRef

M. F H. Al-Kadhemy, Kh. N Abbas, W. B. Abdalmuhdi, "Physical Properties of Rhodamine 6G Laser Dye Combined in Polyvinyl Alcohol films as Heat Sensor", IOP Conference Series: Materials Science and Engineering, 928(7), 072126, (2020).

CrossRef

Y. Khairy, H. A. Elhosiny, I. S. Yahia, H.Y. Zahran, "Facile design of a CUT-OFF laser power attenuation using safranin O-doped PMMA polymeric composite films: Optical spectroscopy and dielectric properties", Optik, 219, 164943, (2020).

CrossRef

J. B. Birks, "Photophysics Aromatic molecules" Wiley and Sons, London. (1971).

I. B. Berlman, "Fluorescence spectra of aromatic molecules" Hand book , Academic press New York ,(1971).

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Published

2022-06-26

How to Cite

[1]
N. A. H. Darweesh, M. F. . Hadi, and A. A. . Saeed, “Investigate Physical Properties and Intensity of Sun Light Transmitted through Safranin/PMMA Films”, MJS, vol. 33, no. 2, pp. 86–92, Jun. 2022.

Issue

Section

Physical Sciences