Absorption Properties of Polyvinyl Alcohol Films Filled with Nanoparticles Doped with Acridine Orange Dye

Authors

  • Fairooz Faeq Kareem Department of Physics College of Science, Mustansiriyah University, Baghdad, IRAQ.
  • Mahasin F. Hadi Department of Physics College of Science, Mustansiriyah University, Baghdad, IRAQ.
  • Asrar Abdulmunem Saeed Department of Physics College of Science, Mustansiriyah University, Baghdad, IRAQ.

DOI:

https://doi.org/10.23851/mjs.v33i2.1103

Keywords:

Acridine Orange, PVA Polymer, Absorption Spectrum, MgO NPs, Al2O3 NPs.

Abstract

Polyvinyl Alcohol (PVA) polymer/ Acridine Orange (AO) dye films prepared via casting technique at room temperature. The effect of adding (Acridine Orange (AO) dye solution, Magnesium Oxide (MgO), and Aluminum Oxide (Al2O3) NPs) to the PVA polymer matrix were studied on the absorption spectra. The effect of AO addition on the absorption spectrum of PVA film is occurrence blue shift (5nm) from 280nm to 275 nm in the PVA and red shift (10nm) from 490nm to be 500 nm for AO maximum absorbance wavelength. The absorbance of AO dye decreases when adding PVA, but increases When the volume ratio of AO dye solution is increased to 0.49 for 18ml, the volume ratio of AO dye solution decreases for 24- and 30-ml volume ratios. Adding NPs led to enhancing the photophysical properties of polymer composite, noted that absorbance of adding alumina nanoparticles more than it is in the case of adding magnesia nanoparticles. Also, there is a 10 nm red shift in AO and a 5 nm blue shift in AO when they are added to the polymer matrix filled with MgO and Al2O3 NPs.

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References

R. Piramidowicz, A. Jusza, L. Lipińska, M. Gil, and P. Mergo, "RE3+:LaALO3 doped luminescent polymer composites," Opt. Mater. (Amst)., vol. 87, no. March, pp. 35-41, 2019, doi: 10.1016/j.optmat.2018.06.018.

CrossRef

M. Nandimath, R. F. Bhajantri, and J. Naik, "Spectroscopic and color chromaticity analysis of rhodamine 6G dye-doped PVA polymer composites for color tuning applications," Polym. Bull., vol. 78, no. 8, pp. 4569-4592, 2021, doi: 10.1007/s00289-020-03332-y.

CrossRef

A. H. El-Sayed, M. A. Hamad, and Y. Hossien, "Physical modifications of polyvinyl alcohol films containing CoCl2," Eur. Phys. J. Plus, vol. 134, no. 11, pp. 0-6, 2019, doi: 10.1140/epjp/i2019-13079-y.

CrossRef

M. Aslam, M. A. Kalyar, and Z. A. Raza, "Polyvinyl alcohol: A review of research status and use of polyvinyl alcohol based nanocomposites," Polym. Eng. Sci., vol. 58, no. 12, pp. 2119-2132, 2018, doi: 10.1002/pen.24855.

CrossRef

O. G. Sathidevi, "Structural properties and its significance of Pva," Int. J. Sci. Technol. Res., vol. 9, no. 2, pp. 6072-6077, 2020.

G. Lv, Z. Li, W. T. Jiang, P. H. Chang, J. S. Jean, and K. H. Lin, "Mechanism of acridine orange removal from water by low-charge swelling clays," Chem. Eng. J., vol. 174, no. 2-3, pp. 603-611, 2011, doi: 10.1016/j.cej.2011.09.070.

CrossRef

V. A. Byvaltsev, M. A. Aliyev, and A. A. Potapov, "Acridine orange: A review of novel applications for surgical cancer imaging and therapy," Front. Oncol., vol. 9, no. SEP, pp. 1-8, 2019.

CrossRef | PubMed

M. Gensicka, Kowalewska, G. Cholewi'nski, and K. Dzierzbicka, "Recent developments in the synthesis and biological activity of acridine/acridone analogues," RSC Adv., vol. 7, no. 26, pp. 15776-15804, 2017.

CrossRef

M. Amina, N. M. Al Musayeib, and N. M. S. Moubayed, "Biogenic green synthesis of MgO nanoparticles using Saussurea costus biomasses for a comprehensive detection of their antimicrobial, cytotoxicity against MCF-7 breast cancer cells and photocatalysis potentials," PLoS One, vol. 15, no. 8 August, pp. 1-23, 2020.

CrossRef | PubMed

S. Pakrashi, N. Chandrasekaran, and A. Mukherjee, "Cytotoxicity of aluminium oxide nanoparticles towards fresh water algal isolate at low exposure concentrations," Aquat. Toxicol., vol. 132-133, pp. 34-45, 2013.

CrossRef | PubMed

V. Kumar, A. Jain, S. Wadhawan, and S. K. Mehta, "Synthesis of biosurfactant-coated magnesium oxide nanoparticles for methylene blue removal and selective Pb2+ sensing," IET Nanobiotechnology, vol. 12, no. 3, pp. 241-253, 2018.

CrossRef

K. Hotta, A. Yamaguchi, and N. Teramae, "Properties of a metal clad waveguide sensor based on a nanoporous-metal- oxide/metal multilayer film," Anal. Chem., vol. 82, no. 14, pp. 6066-6073, 2010.

CrossRef | PubMed

F. F. Kareem, A. A. Saeed, and M. F. H. A.- Kadhemy, "Inspect the Influence of Solvents , Magnesia and Alumina Nanoparticles on Rhodamine 6G Laser Dye Spectroscopic Properties," J. Glob. Sci. Res., vol. 6, no. 9, pp. 1695-1709, 2021.

D. R. Lide, CRC handbook of chemistry and physics, 90 Ed. Taylor and Francis Group LLC, 2010.

M. F. H. Al-Kadhemy, R. Hussein, and Ali A. Dawood Al-Zuky, "Analysis of the Absorption Spectra of Styrene-butadiene in Toluene," J. Phys. Sci., vol. 23, no. 1, pp. 89-100, 2012.

A. A. Ali and Zainab F. Mahdi, "Investigation of nonlinear optical properties for laser dyes-doped polymer thin film," Iraqi J. Phys., vol. 10, no. 19, pp. 54-69, 2012.

M. F. H. Al-Kadhemy, K. N. Abbas, and W. B. Abdalmuhdi, "Physical Properties of Rhodamine 6G Laser Dye Combined in Polyvinyl Alcohol films as Heat Sensor," IOP Conf. Ser. Mater. Sci. Eng., vol. 928, no. 7, pp. 1-10, 2020.

CrossRef

A. M. Wiosetek-Reske, S. Wysocki, and G. W. Ba̧k, "Determination of dipole moment in the ground and excited state by experimental and theoretical methods of N-nonyl acridine orange," Spectrochim. Acta - Part A Mol. Biomol. Spectrosc., vol. 62, no. 4-5, pp. 1172-1178, 2005, doi: 10.1016/j.saa.2005.04.010.

CrossRef | PubMed

S. Chatterjee and G. S. Kumar, "Binding of fluorescent acridine dyes acridine orange and 9-aminoacridine to hemoglobin: Elucidation of their molecular recognition by spectroscopy, calorimetry and molecular modeling techniques," J. Photochem. Photobiol. B Biol., vol. 159, pp. 169-178, 2016, doi: 10.1016/j.jphotobiol.2016.03.045.

CrossRef | PubMed

M. M. Khalil, A. H. El-Sayed, M. S. Masoud, E. M. Mahmoud, and M. A. Hamad, "Synthesis and optical properties of alizarin yellow GG-Cu(II)-PVA nanocomposite film as a selective filter for optical applications," J. Mater. Res. Technol., vol. 11, pp. 33-39, 2021, doi: 10.1016/j.jmrt.2020.12.105.

CrossRef

K. Singh and R. Pal, "Excitation wavelength dependence of emission spectra of polymer films with doped Acridine orange," Int. J. Innov. Reserch Iin Multidiscip. F., vol. 6, no. 5, pp. 254-262, 2020.

N. K. Subramani, S. K. Nagaraj, and H. Siddaramaiah, "Highly Flexible and Visibly Transparent Poly(vinyl alcohol)/Calcium Zincate Nanocomposite Films for UVA Shielding Applications As Assessed by Novel Ultraviolet Photon Induced Fluorescence Quenching," Am. Chem. Soc., vol. 49, no. 7, pp. 2791-2801, 2016, doi: 10.1021/acs.macromol.5b02282.

CrossRef

B. Stojanovic, М. Bukvic, and I. Epler, "Application of aluminum and aluminum alloys in engineering," Appl. Eng. Lett., vol. 3, no. 2, pp. 52-62, 2018.

CrossRef

A. A. Menazea, A. M. Mostafa, and E. A. Al-Ashkar, "Effect of nanostructured metal oxides (CdO, Al2O3, Cu2O) embedded in PVA via Nd:YAG pulsed laser ablation on their optical and structural properties," J. Mol. Struct., vol. 1203, pp. 1-12, 2020, doi: 10.1016/j.molstruc.2019.127374.

CrossRef

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Published

26-06-2022

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Original Article

How to Cite

[1]
F. F. Kareem, M. F. . Hadi, and A. A. . Saeed, “Absorption Properties of Polyvinyl Alcohol Films Filled with Nanoparticles Doped with Acridine Orange Dye”, Al-Mustansiriyah J. Sci., vol. 33, no. 2, pp. 93–97, Jun. 2022, doi: 10.23851/mjs.v33i2.1103.

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