Synthesis, characterization and antibacterial Evaluation for mixed-ligand Complexes of Nickle (II), Manganese(II), Cop-per(II),Cobalt(II) and Mercury(II) with Tetradentate Schiff base and 1,10-phenanthroline
DOI:
https://doi.org/10.23851/mjs.v28i2.503Keywords:
Schiff base, 1, 10-phenanthroline, 4-aminoantipyrine, Mixed ligand complexes.Abstract
An abstract is a brief summary of a research article, thesis, Schiff base ligand (L) was prepared by the reaction of 4-aminantipyrine with o-phenylenediamine, the prepared ligand characterized by Micro elemental Analysis, FT. IR, UV-Vis, and 1H,13C-NMR spectroscopy.complexes of Mn(II), Co(II), Ni(II), Cu(II) and Hg(II) with Schiff base and 1,10-phenanthroline (Phen) have been in-vestigated in aqueous ethanol with (1:1:1) (M:L:Phen). The prepared complexes were character-ized using flame atomic absorption, (C. H. N) Analysis, FT. IR and UV-Vis spectroscopic meth-ods as well as magnetic susceptibility and conductivity measurements. From the obtained data the octahedral structure was suggested for all complexes. The biological screening effects of the in-vestigated compounds were tested against the bacterial species (Staphylococcus aureus), (Esche-richia coli), (Bacillus) and (Pseudomonas) by the good diffusion method.Downloads
References
M. F Tolulope, O. O Olorunfemi, and A. Isaac,"Synthesis and biological properties of N2O2 Schiff bases derived from o-phenylenediamine and substituted salicylal dehydes," vol.6, no.6, pp.816-819, 2014.
M. Aly, A. H Osman., B Abd El-mottled andB. AGouag, "Thermal stability and kinetic studies of Cobalt (II), Nickel (II),Copper(II), Cadmium (II) and Mercury (II) complexes derived from N-salicylide Schiff bases," vol.54, no.4, pp.349-353, 2009.
F. M. Morad,M. El-jail,S. Mand,B. George, " Preparation, physical characterization and antibacterial activity of Ni (II) Schiff Base complex," vol.1, no.1, pp.72-78., 2007.
J. Zhang,Y. Tang,J. Q. Xie, Zeng and C. Weihu, "; Study on phenol oxidation with H2O2 catalyzed by Schiff base manganese complexes as mimetic peroxides," vol.70, no.10, p.1137–1146, 2005. [5] R. a. Y. A. -. D.
N. R. J. Jebe, " Synthesis and spectral study of new azo - azomethine dyes and its copper (II) complexes derived from resorcinol, 4-aminobenzoylhydrazone, and 4-amino antipyrine," no.14, 2011.
M. A Neelakantan,T. Jeyakumar and K. Muthukumaran, " spectral, XRD, SEM and biological activities of transition metal complexes of polydentate ligands containing thiazole moiety," pp.71- 628, 2008.
Z. L. You and H. -L Zhu, "Syntheses, crystal structures, and antibacterial activities of four Schiff base complexes of copper and zinc," vol.630, no.15, pp.2754-2760, 2004.
zinc," vol.630, no.15, pp.2754-2760, 2004.
M. Golcu, H. Tumer, R. Demirelli, and A. Wheatley " Synthesis, characterization, properties and biological activity, Cd (II) and Cu (II) complexes of polydentate Schiff base ligands," vol.358, no.6, pp.1785-1797, 2005.
K. D. KarlinandZ. Tyeklar,Bioinorganic chemistry of copper, vol.5th Edition, New York: Chapman and Hal, 1993.
R. Garg N. Fahmi, andR. V. Singh, " Spectral and biological studies of manganese (II), dioxo molybdenum (VI) and oxovanadium (V) complexes with monobasic bidentate Schiff base ligands," pp.86-670, 2009.
M. F. El-Ghar,N. T. Abdel-Ghani, Y. Badr, and O. MEl-Brady," Synthesis, Spectroscopic and Thermal Studies of Co(II),Ni(II),Cu(II),Zn(II),Cd(II) and Hg(II) with Arylazo Derivatives of 5-amino Pyrazole. ," ISESCO. Science and Technology Vision, vol.3, pp.58-6, 2007.
A. Osole, "Antimicrobial activity and spectral, Magnetic and thermal studies of some transition metal complexes of a Schiff base hydrazone containing a quinoline moiety," vol.3, no.9, p.1080, 2007.
H. Dawood, and N. Jasim, " complexes., Antimicrobial polyester containing Schiff-base metal," J. Coord. Chem., vol.62, no.7, p.1091, 2009.
E. Arai,Y. Nishida,J. Wasa,H. Urakawa andL. Zhuo, "The synthesis, characterization and antimicrobial activity of N,N’-bis (2-Thiophene carbox amide)-1,3-diaminopropane and N,N’-bis(2-furan-carboxamido)-1,3-diamino propane and their Cu (II), Zn (II), Co(II) complexes," Trans. Met. Chem., vol.9, pp.1633-1641, 2008.
H. Hassib andA. A. Razik,"; acetyl acetone, Synthesis and characterization of some transition metals complexes of Schiff base derived from benzidine andand acetylacetone," J. Sci. Appl., vol.2, no.1, pp.83-90, 2008.
F. Karipcin andE. Kabalcilar; Spectroscopic and thermal studies on solid complexes of 4-(2-pyridylazo)-resorcinol with some tran-sition metals, Acta. Chim. Slow.2007, 54 : 242-2472003, p.55.
G. Eason, B. Noble, and I. N. Sneddon, On certain integrals of Lipschitz-Hankel type involving products of Bessel functions, vol. A247, London: Phil. Trans. Roy. Soc, 1955, pp.529-551.
J. C. Maxwell, A Treatise on Electricity and Magnetism, 3rd ed. ed., vol.2, Oxford: Clarendon, 1892, pp.68-73. [19] I. S. Jacobs and C. P. Bean, “Fine particles, thin films and exchange anisotropy, in Magnetism, vol. III, New York: Academic: G. T. Rado and H. Suhl, Eds, 1963, p.271–350.
K. Elissa, "Synthesis and characterization of nickel (II), cobalt (II), manga-nese(II),copper(II),iron(III)and chromi-um(III) complexes of unsymmetrical salen-type ligand and their application as catalyst for the oxidation of styrene J. Indian Chem. Soc., 2009,10(7) p.86- 697.
[1] R. Nicole," Synthesis and characterization of nickel (II), cobalt (II), manga-nese(II),copper(II),iron(III)and chromi-um(III) complexes of unsymmetrical salen-type ligand and their application as catalyst for the oxidation of styrene, J. Indian Chem. Soc., 2006,3(8): 60- 69.
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