Tuning Structural and Optical Properties of WO3 NPs Thin Films by the Fluency of Laser Pulses
DOI:
https://doi.org/10.23851/mjs.v33i3.1145Keywords:
WO3, Thin films, pulsed laser deposition, vacuum , nanoparticlesAbstract
In this paper, tungsten oxide thin films were successfully synthesized by the laser pulse deposition (PLD) method using a pulsed laser (ND-YAG) and wavelength (1064 nm) on a glass substrate at different laser fluencies. The effect of increasing laser fluency, on the optical and structural properties of WO3 nanoparticle thin films, was investigated by UV-Visible spectrophotometer, X-Ray diffraction (XRD), atomic force microscope (AFM) and Scanning Electron Microscope (SEM). X-Ray measurements for all samples of WO3 NPs thin films have shown that by increasing the laser fluencies from 5.175 to 6.369 J/cm2, the intensity of the (2 01) diffraction peak increases due to the film continuing to grow with increased crystallization.
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D. Zhang, Y. Cao, J. Wu and X. Zhang, Tungsten trioxide nanoparticles decorated tungsten disulfide nanoheterojunction for highly sensitive ethanol gas sensing application, Appl. Surf. Sci., 2020, 503, 144063.
X. Chang, S. Xu, S. Liu, N. Wang, S. Sun and X. Zhu, et al., Highly sensitive acetone sensor based on WO3 nanosheets derived from WS2 nanoparticles with inorganic fullerene-like structures, Sens. Actuators, B, 2021, 343, 130135.
A. Staerz, S. Somacescu, M. Epifani, T. Kida, U. Weimar and N. Barsan, WO3-based gas sensors: identifying inherent qualities and understanding the sensing mechanism, ACS Sens., 2020, 5, 1624-1633.
Q. Ding, Y. Wang, P. Guo, J. Li, C. Chen and T. Wang, et al., Cr-doped urchin-like WO3 hollow spheres: the cooperative modulation of crystal growth and energy-band structure for high-sensitive acetone detection, Sensors, 2020, 20, 3473.
S. Liu, W. Zeng and Y. Li, Synthesis of spherical WO3·H2O network for ethanol sensing application, Mater. Lett., 2019, 253, 42-45.
C. Dong, R. Zhao, L. Yao, Y. Ran, X. Zhang and Y. Wang, A review on WO3 based gas sensors: morphology control and enhanced sensing properties, J. Alloys Compd., 2020, 820, 153194.
C.-H. Chang, T.-C. Chou, W.-C. Chen, J.-S. Niu, K.-W. Lin and S.-Y. Cheng, et al., Study of a WO3 thin film based hydrogen gas sensor decorated with platinum nanoparticles, Sens. Actuators, B, 2020, 317, 128145.
H.J. Chen, N.S. Xu, S.Z. Deng, D.Y. Lu, Z.L. Li, J. Zhou, J. Chen, Nanotechnology 18, (2007) 205701.
Y. Hattori, S. Nomura, S. Mukasa, H. Toyota, T. Inoue, T. Kasahara, J. Alloys, Comp. 560 (2013) 105-110.
Y.X. Qin, F. Wang, W.J. Shen, M. Hu, J. Alloys Comp. 540 (2012) 21-26.
L. Fang, S.J. Baik, K.S. Lim, S.H. Yoo, M.S. Seo, S.J. Kang, J.W. Seo, Appl. Phys. Lett. 96 (2010) 193501.
P.J. Barczuk, A. Krolikowska, A. Lewera, K. Miecznikowski, R. Solarska, J. Augustynski, Electrochim. Acta 104 (2013) 282-288.
M. Vasilopoulou, L.C. Palilis, D.G. Georgiadou, A.M. Douvas, P. Argitis, S. Kennou, L. Sygellou, G. Papadimitropoulos, I. Kostis, N.A. Stathopoulos, D. Davazoglou, Adv. Funct. Mater. 21 (2011) 1489-1497.
J. Meyer, S. Hamwi, S. Schmale, T. Winkler, H.H. Johannes, T. Riedl, W. [29] W.L. Kwong, N. Savvides, C.C. Sorrell, Electrochim. Acta 75 (2012) 371-380.
S.M. Yong, T. Nikolay, B.T. Ahn, D.K. Kim, J. Alloys Comp. 547 (2013) 113-117.
N.S. Ramgir, C.P. Goyal, P.K. Sharma, U.K. Goutam, S. Bhattacharya, N. Datta, M. Kaur, A.K. Debnath, D.K. Aswal, S.K. Gupta, Sens. Actuators B - Chem. 188, (2013) 525-532.
D.S. Lee, K.H. Nam, D.D. Lee, Thin Solid Films 375 (2000) 142-147.
D. Manno, A. Serra, M. DiGiulio, G. Micocci, A. Tepore, Thin Solid Films 324, (1998) 44-51.
M.G. Hutchins, O. Abu-Alkhair, M.M. El-Nahass, K. Abd El-Hady, Mater. Chem., Phys. 98 (2006) 401-405.
A. Rothschild, J. Sloan, R. Tenne, J. Am. Chem. Soc. 122 (2000) 5169-5179.
R.S. Vemuri, G. Carbjal-Franco, D.A. Ferrer, M.H. Engelhard, C.V. Ramana, Appl., Surf. Sci. 259 (2012) 172-177.
C. Zhang, A. Boudiba, P.D. Marco, R. Snyders, M.G. Olivier, M. Debliquy, Sens. Actuators B - Chem. 181 (2013) 395-401.
R. Sivakumar, A. Moses Ezhil Raj, B. Subramanian, M. Jayachandran Trivedi, C. Sanjeeviraja, Mater. Res. Bull. 39 (2004) 1479-1489.
Z. Silvester Houweling, John W. Geus, Michiel de Jong, Peter-Paul R.M.L. Harks, Karine H.M. van der Werf, Ruud E.I. Schropp, Mater. Chem. Phys. 131 (2011), 375-386.
K.J. Lethy, D. Beena, R.V. Kumar, V.P.M. Pillai, V. Ganesan, V. Sathe, Appl. Surf. Sci. 254 (2008) 2369-2376.
S. Yamamoto, A. Inouye, M. Yoshikawa, Nucl. Instrum. Methods B 266 (2008), 802-806.
L.M. Bertus, C. Faure, A. Danine, C. Labrugere, G. Campet, A. Rougier, A. Duta, Mater. Chem. Phys. 140 (2013) 49-59.
P.M. Kadam, N.L. Tanwal, P.S. Shinde, S.S. Mali, R.S. Patil, A.K. Bhosale, H.P. Deshmukh, P.S. Patil, J. Alloys Comp. 509 (2011) 1729-1733.
W.L. Kwong, N. Savvides, C.C. Sorrell, Electrochim. Acta 75 (2012) 371-380
B. Ingham, S.V. Chong, J.L. Tallon, Curr. Appl. Phys. 4 (2004) 202-205.
N. Naseri, H. Kim, W. Choi, A.Z. Moshfegh, Int. J. Hydrogen Energy 38 (2013), 2117-2125.
R. Solarska, B.D. Alexander, A. Braun, R. Jurczakowski, G. Fortunato, M. Stiefel, T. Graule, J. Augustynski, Electrochim. Acta 55 (2010) 7780-7787.
C.V. Ramana, G. Baghmar, E.J. Rubio, M.J. Hernandez, ACS Appl. Mater. Int. 5, (2013) 4659-4666.
H.H. Lu, J. Alloys Comp. 465 (2008) 429-435.
S. Keshri, A. Kumar, D. Kabiraj, Thin Solid Films 526 (2012) 50-58.
K.J. Patel, C.J. Panchal, V.A. Kheraj, M.S. Desai, Mater. Chem. Phys. 114 (2009) 475-478.
R. Binions, C. Piccirillo, R.G. Palgrave, I.P. Parkin, Chem. Vapor Depos. 14 (2008) 33-39.
A.Z. Mohammed, N.J. Mohammed, I.K. Khudhair, "Effect of the Number Shots of Laser on Structural Transformations and Optical Properties of ZnS Nanoparticles Thin Films," Arab J. Nucl. Sci. Appl., vol. 51, 4, pp. 108-117, 2018.
Lethy, K. J., Beena, D., Kumar, R. V., Pillai, V. M., Ganesan, V., & Sathe, V. (2008). Structural, optical and morphological studies on laser ablated nanostructured WO3 thin films. Applied Surface Science, 254(8), 2369-2376,
Cullity, B. D. Elements of X-ray Diffraction. Addison-Wesley Publishing, 1956.
N. J. Mohammed, H. A. Ahmed, "Effect of Laser Fluence on Structural Transformations and Photoluminescence Quenching of Zinc Selenide Nanoparticles Thin Films", Al-Mustansiriyah Journal of Science, Volume 29, Issue 4, PP 122-127, 2018.
Corona, S. A. M., Souza, A. E. D., Chinelatti, M. A., Borsatto, M. C., Pécora, J. D., & Palma-Dibb, R. G.' Effect of energy and pulse repetition rate of Er: YAG laser on dentin ablation ability and morphological analysis of the laser-irradiated substrate'. Photomedicine and Laser Therapy, 25(1), 26-33. (2007).
Shaker, S. S. 'Preparation and Study the Characteristics of Tungsten Trioxide Thin Films for Gas Sensing Application', Engineering and Technology Journal, 34, (2016).
E. A. Davis, N. F. Mott, Phil. Mag. 22, 903, (1970).
Díaz-Reyes, J., Castillo-Ojeda, R., Galván-Arellano, M., & Zaca-Moran, O. 'Characterization of WO3 thin films grown on silicon by HFMOD, Advances in Condensed Matter Physics, 2013.
Zou, Y. S., Zhang, Y. C., Lou, D., Wang, H. P., Gu, L., Dong, Y. H., ... & Zeng, H. B.. Structural and optical properties of WO3 films deposited by pulsed laser deposition. Journal of alloys and compounds, 583, 465-470, 2014.
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