Structural Properties of Nanoparticles TiO2/PVA Polymeric Films

Authors

  • Samara A. Madhloom Department of Physics, College of Science, Mustansiriyah University, IRAQ.

DOI:

https://doi.org/10.23851/mjs.v28i2.517

Keywords:

Nanoparticle doped polymer, PolyVinyl Alcohol (PVA), Titanium dioxide (TiO2), Structure Properties, X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM)

Abstract

In this research, X-ray diffraction of the powder (PVA polymer, titanium dioxide with two parti-cle sizes) and (TiO2 (15.7 nm)/PVA and TiO2 (45.7 nm)/PVA) films have been studied,the amount of polymer is (0.5) g and (0.01)g from each particle sizes of nanoparticles will be used. Casting method is used to prepare homogeneous films on glass petri dishes. All parameters ac-counted for the X-ray diffraction; full width half maximum (FWHM), Miller indices (hkl), size of crystalline (D), Specific Surface Area (S) and Dislocation Density (δ). The nature of the structural of materials and films will be investigated. The XRD pattern of PVA polymer has semi-crystalline nature and the titanium dioxide with two particle sizes have crystalline structure; ana-tase type. While the mixture between these materials led to appearing some crystalline peaks into XRD pattern of PVA polymer

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References

S. K. Saxena, (2004), Polyvinyl Alcohol (PVA), Chemical and Technical Assess-ment 61st JECFA,1-3.

C. M. Hassan, N. A. Peppas, (2000), Struc-ture and Applications of Poly (vinyl alco-hol) Hydrogels Produced by Conventional Crosslinking or by Freezing/Thawing Methods, Adv. Polym. Sci., 153, 37-65.

C. C Demerlis, D. R. Schoneker, (2003), Review of the oral toxicity of polyvinyl al-cohol (PVA), Food Chem. Toxicol, 41, 319–326.

J. C. J. F Tacx, H. M. Schoffeleers, A. G. M. Brands, L. Teuwen, (2000), Dissolution Behavior and Solution Properties of Poly-vinylalcohol as Determined by Viscometry and Light Scattering in DMSO, Ethylene Glycol and Water, Polymer, 41, 947-957.

J. F. Banfield, A. Navrotsky, (2001), Na-noparticles and the Environment, Miner-alogical Society of America, Washington, D. C.

A. Kumar, S. P. Hsun Lo and S. M Chen, (2008), Electrochemical synthesis and characterization of TiO2 nanoparticles and their use as a platform for flavin adenine dinucleotide immobilization and efficient electrocatalysis, Nanotechnology, 19, 255501-255507.

A. F. Saleh, A. M. Jaffar, N. A. Samoom and M. W. Mahmmod, (2014), Effect Add-ing PVA Polymer on Structural and Opti-cal Properties of TiO2 Thin Films, Journal of Al-Nahrain University, 17 (2), 116-121.

M. Vishwas, K. N. Rao, D. N. Priya, A. M. Raichur, R. P. S. Chakradhar and K. V. Warlu, (2014), Effect of TiO2 nano-particles on Optical, electrical and Me-chanical Properties of Poly (vinyl Alcohol) Films, Procedia Materials Science, 5, 247-254.

A. M. Shehap and D. S. Akil, (2016), Structural and optical properties of TiO2 nanoparticles/PVA for different compo-

sites thin films, Int. J. Nanoelectronics and Materials, 9, 17-36.

Jia-Guo Yu, Xiu-Jian Zhao, Huo-Gen Yu, Bei Cheng, Wing-Kei Ho, (2003), physical chemistry, The Effect of Calcination Tem-perature on the Surface Microstructure and Photocatalytic Activity of TiO2 Thin Films Prepared by Liquid Phase Deposition, B 107 (50) ,13871-13879.

L. C. Nehru, V. Swaminathan, C. Sanjeevi-raja, (2012), Photoluminescence Studies on Nanocrystalline Tin Oxide Powder for Op-toelectronic Devices, American. J. Mat. Sci., 2(2): 6-10.

D. B. Sirdeshmukh, L. Sirdeshmukh, K. G. Subhadra, (2006), Micro- and Macro-Properties of solids: Thermal, Mechanical and Dielectric properties,Springer, NewYork.

Y. P. V. Subbaiah, P. Prathap, K. T. R. Reddy, (2006), Structural, electrical and optical properties of ZnS films deposited by close-spaced evaporation. Appl. Surf. Sci., 253(5): 2409-2415.

M. S. Jalil, (2015),Physical Properties, An-tibacterial and antibiofilm Activities of PVA Polymer with Safranin Dye and Bio-surfactant, Ph. D Thesis, College of Sci-ence, Al-Mustansiriyah University.

K. K. Senapati, Ch. Borgohain and P. Phukan, (2012), CoFe2O2-ZnS nanocom-posite: a magnetically recyclable photo-catalyst, Electronic Supplementary Materi-al (ESI) for Catalysis Science and Tech-nology.

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Key Dates

Published

11-04-2018

Issue

Section

Original Article

How to Cite

[1]
S. A. Madhloom, “Structural Properties of Nanoparticles TiO2/PVA Polymeric Films”, Al-Mustansiriyah Journal of Science, vol. 28, no. 2, pp. 188–195, Apr. 2018, doi: 10.23851/mjs.v28i2.517.

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