Synthesis, characterization and antibacterial Evaluation for mixed-ligand Complexes of Nickle (II), Manganese(II), Cop-per(II),Cobalt(II) and Mercury(II) with Tetradentate Schiff base and 1,10-phenanthroline
Keywords:Schiff base, 1, 10-phenanthroline, 4-aminoantipyrine, Mixed ligand complexes.
AbstractAn abstract is a brief summary of a research article, thesis, Schiff base ligand (L) was prepared by the reaction of 4-aminantipyrine with o-phenylenediamine, the prepared ligand characterized by Micro elemental Analysis, FT. IR, UV-Vis, and 1H,13C-NMR spectroscopy.complexes of Mn(II), Co(II), Ni(II), Cu(II) and Hg(II) with Schiff base and 1,10-phenanthroline (Phen) have been in-vestigated in aqueous ethanol with (1:1:1) (M:L:Phen). The prepared complexes were character-ized using flame atomic absorption, (C. H. N) Analysis, FT. IR and UV-Vis spectroscopic meth-ods as well as magnetic susceptibility and conductivity measurements. From the obtained data the octahedral structure was suggested for all complexes. The biological screening effects of the in-vestigated compounds were tested against the bacterial species (Staphylococcus aureus), (Esche-richia coli), (Bacillus) and (Pseudomonas) by the good diffusion method.
M. F Tolulope, O. O Olorunfemi, and A. Isaac,"Synthesis and biological properties of N2O2 Schiff bases derived from o-phenylenediamine and substituted salicylal dehydes," vol.6, no.6, pp.816-819, 2014.
M. Aly, A. H Osman., B Abd El-mottled andB. AGouag, "Thermal stability and kinetic studies of Cobalt (II), Nickel (II),Copper(II), Cadmium (II) and Mercury (II) complexes derived from N-salicylide Schiff bases," vol.54, no.4, pp.349-353, 2009.
F. M. Morad,M. El-jail,S. Mand,B. George, " Preparation, physical characterization and antibacterial activity of Ni (II) Schiff Base complex," vol.1, no.1, pp.72-78., 2007.
J. Zhang,Y. Tang,J. Q. Xie, Zeng and C. Weihu, "; Study on phenol oxidation with H2O2 catalyzed by Schiff base manganese complexes as mimetic peroxides," vol.70, no.10, p.1137–1146, 2005.  R. a. Y. A. -. D.
N. R. J. Jebe, " Synthesis and spectral study of new azo - azomethine dyes and its copper (II) complexes derived from resorcinol, 4-aminobenzoylhydrazone, and 4-amino antipyrine," no.14, 2011.
M. A Neelakantan,T. Jeyakumar and K. Muthukumaran, " spectral, XRD, SEM and biological activities of transition metal complexes of polydentate ligands containing thiazole moiety," pp.71- 628, 2008.
Z. L. You and H. -L Zhu, "Syntheses, crystal structures, and antibacterial activities of four Schiff base complexes of copper and zinc," vol.630, no.15, pp.2754-2760, 2004.
zinc," vol.630, no.15, pp.2754-2760, 2004.
M. Golcu, H. Tumer, R. Demirelli, and A. Wheatley " Synthesis, characterization, properties and biological activity, Cd (II) and Cu (II) complexes of polydentate Schiff base ligands," vol.358, no.6, pp.1785-1797, 2005.
K. D. KarlinandZ. Tyeklar,Bioinorganic chemistry of copper, vol.5th Edition, New York: Chapman and Hal, 1993.
R. Garg N. Fahmi, andR. V. Singh, " Spectral and biological studies of manganese (II), dioxo molybdenum (VI) and oxovanadium (V) complexes with monobasic bidentate Schiff base ligands," pp.86-670, 2009.
M. F. El-Ghar,N. T. Abdel-Ghani, Y. Badr, and O. MEl-Brady," Synthesis, Spectroscopic and Thermal Studies of Co(II),Ni(II),Cu(II),Zn(II),Cd(II) and Hg(II) with Arylazo Derivatives of 5-amino Pyrazole. ," ISESCO. Science and Technology Vision, vol.3, pp.58-6, 2007.
A. Osole, "Antimicrobial activity and spectral, Magnetic and thermal studies of some transition metal complexes of a Schiff base hydrazone containing a quinoline moiety," vol.3, no.9, p.1080, 2007.
H. Dawood, and N. Jasim, " complexes., Antimicrobial polyester containing Schiff-base metal," J. Coord. Chem., vol.62, no.7, p.1091, 2009.
E. Arai,Y. Nishida,J. Wasa,H. Urakawa andL. Zhuo, "The synthesis, characterization and antimicrobial activity of N,N’-bis (2-Thiophene carbox amide)-1,3-diaminopropane and N,N’-bis(2-furan-carboxamido)-1,3-diamino propane and their Cu (II), Zn (II), Co(II) complexes," Trans. Met. Chem., vol.9, pp.1633-1641, 2008.
H. Hassib andA. A. Razik,"; acetyl acetone, Synthesis and characterization of some transition metals complexes of Schiff base derived from benzidine andand acetylacetone," J. Sci. Appl., vol.2, no.1, pp.83-90, 2008.
F. Karipcin andE. Kabalcilar; Spectroscopic and thermal studies on solid complexes of 4-(2-pyridylazo)-resorcinol with some tran-sition metals, Acta. Chim. Slow.2007, 54 : 242-2472003, p.55.
G. Eason, B. Noble, and I. N. Sneddon, On certain integrals of Lipschitz-Hankel type involving products of Bessel functions, vol. A247, London: Phil. Trans. Roy. Soc, 1955, pp.529-551.
J. C. Maxwell, A Treatise on Electricity and Magnetism, 3rd ed. ed., vol.2, Oxford: Clarendon, 1892, pp.68-73.  I. S. Jacobs and C. P. Bean, “Fine particles, thin films and exchange anisotropy, in Magnetism, vol. III, New York: Academic: G. T. Rado and H. Suhl, Eds, 1963, p.271–350.
K. Elissa, "Synthesis and characterization of nickel (II), cobalt (II), manga-nese(II),copper(II),iron(III)and chromi-um(III) complexes of unsymmetrical salen-type ligand and their application as catalyst for the oxidation of styrene J. Indian Chem. Soc., 2009,10(7) p.86- 697.
 R. Nicole," Synthesis and characterization of nickel (II), cobalt (II), manga-nese(II),copper(II),iron(III)and chromi-um(III) complexes of unsymmetrical salen-type ligand and their application as catalyst for the oxidation of styrene, J. Indian Chem. Soc., 2006,3(8): 60- 69.
How to Cite
Articles accepted for publication in Al-Mustansiriyah Journal of Science (MJS) are protected under the Creative Commons Attribution 4.0 International License (CC-BY-NC). Authors of accepted articles are requested to sign a copyright release form prior to their article being published. All authors must agree to the submission, sign copyright release forms, and agree to be included in any correspondence between MJS and the authors before submitting a work to MJS. For personal or educational use, permission is given without charge to print or create digital copies of all or portions of a MJS article. However, copies must not be produced or distributed for monetary gain. It is necessary to respect the copyright of any parts of this work that are not owned by MJS.