Study of Physical Properties for Sodium acetate with Water and Water - Acetone mixtures at Different Temperatures
Keywords:sodium acetate, molecular interactions, density, viscosity, apparent molal volume, Jones–Dole equation.
In this study binary and ternary solutions are prepared by using the sodium acetate concentrations (0.1, 0.125, 0.2, 0.25, 0.4, 0.5, 0.8, 1 M) in water and acetone –water mixtures .The important parameters such as apparent molal volume, the partial molal volume transfer, apparent molal compressibility, free energy of activation of viscous flow and thermodynamic activation parameter (enthalpy and entropy) determined of sodium acetate in water , 20%, 40% ,60% and 80% V/V acetone –water mixtures at 298.15K, 303.15K, and 308.15K from density and viscosity measurements espectively. The limiting apparent molal volumes and experimental slopes were derived from the Masson equation, have been interpreted in terms of solute–solvent and solute–solute interactions respectively. The viscosity data were analyzed using theJones–Dole equation and the derived parameter B - coefficient has also been interpreted in terms of solute–solvent interactions in the solutions.
Strokes R.H and Mills R, “viscosity of electrolytes and related properties”, (Pergman Press, New York), 1965.
Nightingale R.R “Chemical Physics of ionic solutions” edited by B.E.Conway and R.G Barrades”, (John Wiley, New York),295, 1965.
Aswale S,R; Aswale S,S and HajareS. Relative association, specific relaxation time and free volume of antibiotic ampicillin sodium, J. Chem. Pharm. Res.,4(8), 3783-3791,2012.
Wadekar M,P. Thermo acoustical molecular interaction study of azomethine and its Fe (III) metal complex using ultrasonic technique J. Chem. Pharm. Res., 5(8), 37-41,2013.
Hemalatha B., Vasantharani P. and Senthilkumar N., Solute-Solvent and Solute-Solute Interactions of Tetrabutylammonium Bromide in DMF-Water Systems at Different temperatures, International Journal of Advances in Engineering & Technology, 6( 2), 795-803,2013.
Thakur R.C. ,Sharma R , Kumar A and Parmar M.L., Thermodynamic and transport studies of some aluminium salts in water and binary aqueous mixtures of tetrahydrofuran, J. Mater. Environ. Sci. 6 (5), 1330-1336 ,2015.
Ayranci E., Apparent Molar Volume and Viscosity of Compounds with Asymmetric Carbon Atoms, Journal of Chemical and Engineering Data, 42(5), 934–937,1997.
Sastry N.V., Vaghela N. M., Pradip and Macwan M. .,Densities, excess molar and partial molar volumes for water + 1-butyl- or, 1-hexyl- or, 1-octyl-3-methylimidazolium halide room temperature ionic liquids at T = (298.15 and 308.15) K. J, Mol. Liquids, 18012–18018. 2013.
Malasane P,R. Study of Interactions of Tryptophan through Acoustic and Thermo dynamic Properties, Research Journal of Chemical Sciences, 3(8), 73-77,2013.
Roy M,N; Chanda R and Sarkar B,K.Apparent molar volume, viscosity, and adiabatic compressibility of some mineral sulfates in aqueous binary mixtures of formamide at 298.15, 308.15, and 318.15 K, Russ. J. Phy. Chem. A, 83(10), 1737-1746, 2009.
Imai T. Molecular theory of partial molar volume and its applications to biomolecular systems , Condensed Matter Phys.,10(3), 343-361,2007.
Roy M,N; Dakua V,K and Sinha B. Partial Molar Volumes, Viscosity B-Coefficients, and Adiabatic Compressibilities of Sodium Molybdate in Aqueous 1,3-Dioxolane Mixtures from 303.15 to 323.15K, Int. J. Thermophys., 28, 1275-1284,2007.
Pal A, Ramniwas and Chauhan N, Volumetric and ultrasonic studies of glycine in binary aqueous solutions of mannose, maltose and raffinose at different temperatures, Indian J Chem.,49A, 1309-1317,2010.
Riddick J,A.; Bunger W,B and Sakano T,K., "Techniques of Chemistry" Volume II, Organic Solvents, Wiley, New York 1986.
ZamirT, KhanA, Durrani S and Uddin F. Study of ion–solvent interactions and activation energy of LiBr in DMSO, H2O and DMSO–H2O mixtures at various temperatures. Ionics;13, 245-255,2007.
Jones G and Dole M., The viscosity of aqueous solutions of strong electrolytes with special reference to barium chloride, Journal of the American Chemical Society, 51, 2950–2964 ,1929.
Thirumaran S and Sathish K., Molecular Interionic Interaction Studies of Some Divalent Transition Metal Sulphates in Aqueous Ethylene Glycol at Different Temperatures, Research Journal of Chemical Sciences,1(8), 63-71, 2011.
Millero F,J. Losurdo A and Shin C., The apparent molal volumes and adiabatic compressibilities of aqueous amino acids at 25⁰C, The Journal of Physical Chemistry, 82, 784–792 ,1978.
Glasstone S, Laidler K, J and Eyring H,. The theory of Rate Processes, Mc Graw Hill, New YorK, 1941.
Dey P, Muhamman A, M and Entaazul M, H,.Apparent Molar Volume and Viscosity Studies on Some Carbohydrates in Solutions, Monatshefte Fur Chemie.,134(6), 797-809,2003.
Jabeen S, Akber S and Uddin F.Activation Parameter of Butane and DecaneSulfunic Acids and mixed Solvents at Different Temperatures by viscosity Measurements .Pak .J SciInd Res, 43(1),1-6,2000.
Khan M,S., RehmanA. and Khan N, M.Thermodynamic and Viscometric studies of PolyButadiene Rubber in Teluene at various Temperatures, Pak J Ind Res; 42(3):117-120,1999.
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