Synthesis and Characterization of New Silver (I) N-Heterocyclic Ccarbene Ccomplex Dderived from Imidazol-2-ylidene salt
| Dublin Core | PKP Metadata Items | Metadata for this Document | |
| 1. | Title | Title of document | Synthesis and Characterization of New Silver (I) N-Heterocyclic Ccarbene Ccomplex Dderived from Imidazol-2-ylidene salt |
| 2. | Creator | Author's name, affiliation, country | Mohammedl Mujbe Hasson; Department of Chemistry, College of Science, Mustansiriyah University, IRAQ; Iraq |
| 3. | Subject | Discipline(s) | |
| 3. | Subject | Keyword(s) | Heterocyclic carbene, Silver complexes |
| 4. | Description | Abstract | A new N, N'-imidazolium salt 1-(2,6-diisopropylphenyl)-3- (4,6-dimorpholino -1,3,5-traizine-2-yl)-1H-imidazol-3-ium chloride) as a precursor of N - heterocyclic carbene ligand was prepared via the reaction of 1 - (2, 6 - diisopropyl phenyl - 1H - imidazole) with 1, 3, 5 - triazine derivative bearing morpholine substituent (2, 6 -dimorpholine - 6- chloro-1, 3, 5-triaziazine). Linear coordi-nated Ag (І) NHC complex was synthesised via deprotonation of the imidazolium salt and reac-tion with Ag2O in darkness at room temperature by in situ method. The complex was synthesised for using as transfer agent to prepare another transition metals complexes by transmetallation method in the future. The imidazolium salt and their silver complex have been characterized by 1 H and 13C NMR spectroscopy as well as mass spectrometry. |
| 5. | Publisher | Organizing agency, location | Mustansiriyah University |
| 6. | Contributor | Sponsor(s) | |
| 7. | Date | (YYYY-MM-DD) | 2018-04-11 |
| 8. | Type | Status & genre | Peer-reviewed Article |
| 8. | Type | Type | |
| 9. | Format | File format | |
| 10. | Identifier | Uniform Resource Identifier | http://mjs.uomustansiriyah.edu.iq/ojs1/index.php/MJS/article/view/500 |
| 10. | Identifier | Digital Object Identifier (DOI) | http://dx.doi.org/10.23851/mjs.v28i2.500 |
| 11. | Source | Title; vol., no. (year) | Al-Mustansiriyah Journal of Science; Vol 28, No 2 (2017) |
| 12. | Language | English=en | en |
| 14. | Coverage | Geo-spatial location, chronological period, research sample (gender, age, etc.) | |
| 15. | Rights | Copyright and permissions |
Copyright (c) 2018 Al-Mustansiriyah Journal of Science This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. |