Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)
| Dublin Core | PKP Metadata Items | Metadata for this Document | |
| 1. | Title | Title of document | Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II) |
| 2. | Creator | Author's name, affiliation, country | Al-Ameen Bariz Omar Ali; Departement of Chemistry, College of Science, Mustansiriyah University, IRAQ |
| 3. | Subject | Discipline(s) | |
| 3. | Subject | Keyword(s) | Schiff base ligands, Thiosemicarbazones, Kinetic study |
| 4. | Description | Abstract | Cyclohexane-1,2-bis(thiosemicarbazone) (CHTSC) was synthesized via the condensation reaction of cyclohexane-1,2-dione and thiosemicarbazide. Series of metal complexes of the prepared lig-and, of general formula [M(CHTSC)(NO3)2], were reported. The prepared coordination complex-es were characterized and their structures elucidated using different techniques. These showed that all complexes are octahedral geometries. The kinetics of the formation of these complexes have been investigated using stopped-flow spectrophotometry. These studies revealed that the reactions are completed on the second’s timescale with 1st-order dependence (either on the con-centration of metal salt or on the concentration of CHTSC). |
| 5. | Publisher | Organizing agency, location | Mustansiriyah University |
| 6. | Contributor | Sponsor(s) | |
| 7. | Date | (YYYY-MM-DD) | 2018-04-11 |
| 8. | Type | Status & genre | Peer-reviewed Article |
| 8. | Type | Type | |
| 9. | Format | File format | |
| 10. | Identifier | Uniform Resource Identifier | http://mjs.uomustansiriyah.edu.iq/ojs1/index.php/MJS/article/view/499 |
| 10. | Identifier | Digital Object Identifier (DOI) | http://dx.doi.org/10.23851/mjs.v28i2.499 |
| 11. | Source | Title; vol., no. (year) | Al-Mustansiriyah Journal of Science; Vol 28, No 2 (2017) |
| 12. | Language | English=en | en |
| 14. | Coverage | Geo-spatial location, chronological period, research sample (gender, age, etc.) | |
| 15. | Rights | Copyright and permissions |
Copyright (c) 2018 Al-Mustansiriyah Journal of Science This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. |