Synthesis and Characterization of Nanostructure Tio2/Anthraquenone (AQ) Prepared by Sol-Gel Method

Fadhela M. Hussein

Abstract


sol–gel technique conducted to synthesize nano titanium dioxide with anthraquenone (AQ) relatively in acidic pH. Nanoparticles were characterized using techniques like, Scanning Electrion Microscope (SEM), Atomic Force Microscope (AFM), UV-Visible Spectrioscopy, X-ray diffraction (XRD), Fourier transform infrared (FT-IR), SEM picture display that the TiO2/AQ is spherical in style, the band gap of TiO2/AQ nanoparticle is (3.05eV), BET and BJH analysis provides Pore volume and specific Surface area and the kinetic studie Suggest that the reaction is pseudo first order and the rate of reaction was reduce with rising initial concentration for p-Nitrotolune.

Keywords


sol–gel, Nanoparticles, Atomic Force Microscope, Nanostructure.

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References


R. X. Hailin.L, "photocatalytic activity of Mo+ Fe Co-doped Titanium Dioxide Nanoparticles prepared by Sol-Gel method, " Vol 28, No.1, p. 44, 2012.

C. W.-N. C. C.-F. Hua.D, "Low temperature preparation of Nano TiO2 and its application as antibacterial agents, " Trans Nonferrous Met.Soc.China 17, pp. 700-703, 2007.

I.-H. Amin.N.M, "synthesis and characterization of Nano-structure TiO2 thin film prepared by sol-gel spin coating method, " Journal of Applied Sciences Research.Vol.9, No.3, pp. 1960-1965, 2013.

K. F. Byranand.M.M, " Review on synthesis of Nano-TiO2 via Different Methods, " J.of Nanostructures 3, pp. 1-9, 2013.

A. Sayilkan.F, "Characterization of TiO2 Synthesized in Alcohol by a sol-gel process: the effects of annealing temperature and acid catalyst, " Turk.J.Chem 29, pp. 697-706, 2005.

C. Qi.L, "Synthesis and characterization of CdS nanoparticles stabilized by double -Hydrophilicblock copolymers, " Nano letters, Vol 1, No.2, pp. 61-65, 2001. CrossRef

A. A. Thangavelu.K, "Preparation and characterization of Nanosized TiO2 powder by sol-gel precipitation Route, " International Journal of Emerging Technology and Advanced Engineering, Vol 3, No.1, 2013.

R. Vijaylakshmi.R, "Synthesis and characterization of Nano-TiO2 Via different methods, "Scholars Research Library Archives of applied Science Research.Vol 4, No.2, pp. 1183-1190, 2012.

P. J. Stefanska.K.S, "The influence of addition of a catalyst and chelating agent on the properties of titanium dioxide synthesized Via the sol-gel method, " J. Sol-Gel Sci. Technol, 75, pp. 264-278, 2015. CrossRef

L. S. B. O. Starowicz.Z, "Photochemical silver nanoparticales deposition on sol-gel TiO2 for plasmonic properties utilization, " J.Sol-Gel.Sci Technol.73, pp. 563-571, 2015. CrossRef

V. S. R. Balachandran.K, "Synthesis of nano TiO2-SiO2 composite using Sol-Gel method: effect on size, surface morphology and thermal stability, " International Journal of Engineering Science and Technology, Vol 2, No.8, pp. 3695-3700, 2010.

N. Tumuluir.A, "Band gap determination using Tauces plot for LiNbO3 thin films, " International Journal of Chem. Tech. Research.Vol.6, No.6, pp. 3353-3356, 2014.

N. Komarneni S., "Solvothermal Hydro-thermal synthesis of metal oxides and metal powders with and without microwaves, " Verlag der Zeitschrift fur naturfoe schung, Tubingen, 65, pp. 1033-1037, 2010.

L. C. D. Trinh.D.T.T, "Investigation of intermediate compounds of phenol in photocatalysis process, " International Journal of chemical engineering and applications, Vol 7, No.4, 2016. m. H. L. Friesen.D.A, "Factors influencing relative efficiency in photo-oxidations of organic molecules by Cs3PWO and TiO2 colloidal photocatalysts, " Journal of photochemistry and photobiology A, Vol.133, No.3, pp. 213-220, 2000.




DOI: http://dx.doi.org/10.23851/mjs.v28i1.316

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