A simple Spectrophotometric Evaluation Method Of Allura Red (E129) in The several Samples Using Cloud Point Extraction

mohammed zaboon thani

Abstract


Cloud point extraction (CPE) method was successfully used for estimation and preconcentration of Allura red (E129) by spectrophotometry. The procedure was depended on the extraction of Allura red as an ion pair with cetyl pyridinium chloride  from aqueous solution using a nonionic surfactant TX-114 or Brij-35. The absorbance of the extracted surfactant- rich phase was measured at 507 nm after diluted with water.The influence of different factors on  cloud point extraction(CPE) of Allura red such as pH media  ,equilibrium temperature ,incubation time , concentration of surfactant and electrolyte concentration was investigated.Calibration graph was linear in a concentration range between 2-40 µgml-1 of Allura red with correlation coefficient r= 0.9998 for TX-114 and 0.9992 for Brij-35 .The developed procedure was applied to estimation and preconcentration of Allura red in the different beverages

Keywords


Allura Red,Spectrophotometric,Cloud Point Extraction,Beverages

Full Text:

PDF

References


F.U.Chiuminatto, E.Mazzucco, G.Calabrese, M.C.Gennaro and E.Marengo, Non-target screening of allura red AC photodegradation products in a beverage through ultra high performance liquid chromatography coupled with hybrid triple quadrupole/linear ion trap mass spectrometry , 136, Food Chemistry , 2013,617-23.

M.S. El-Shahawi, A. Hamza, A.A. Al-Sibaai, A.S. Bashammakh and H.M. Al-Saidi , new method for analysis of sunset yellow in food samples based on cloud point extraction prior to spectrophotometric determination , 19, J. Ind. Eng. Chem., 2013,529-535.

N. Pourreza , S. Rastegarzadeh and A. Larki , Determination of allura red in food samples after cloud point extraction using mixed micelles , 126, Food Chemistry , 2011, 1465-1469.

H. Elham and T. Reza , Simultaneous spectrophotometric determination of synthetic dyes in food samples after cloud point extraction using multipleresponse optimizations , 148, Talanta , 2016,237-246.

M. Soylak , Y.E. Unsal and M. Tuzen , Spectrophotometric determination of trace levels of allura red in water samples after separation and preconcentration , 49, Food Chemistry , 2011,1183-1187.

M. Alesso , G. Bondioli , M.C. Talio , M.O. Luccom and L.P. Fernandez , Micelles mediated separation fluorimetric methodology for Rhodamine B determination in condiments.snacks and candies , 134,Food Chemistry , 2012,513-517.

E.I. de Andrade , M.I.F. Guedes , I.G.P. Vieira and F.N.P. Mendes , Rodrigues , P.A.S.;Maia , C.S.C.;Avila , M.M.M.;de Matos , L. Determination of synthetic food dyes in commercial soft drinks by TLC and ion-pair HPLC , 157, Food Chemistry , 2014,193-198.

T. Zou , P. He , A. Yasen and Z. Li , Determination of seven synthetic dyes in animal feeds and meat by high performance liquid chromatography with diode array and tandem mass detectors , 138,Food Chemistry , 2013,1742-1748.

N. Dossi , R. Toniolo , A. Pizzariello , S. Susmel , F. Perennes and G. Bontempelli , A capillary electrophoresis microsystem for the rapid in –channel amperometric detection of synthetic dyes in food , 601, J. Electroanal. Chem. , 2007,1-7

A.H. El-sheikh and Y.S. Al-degs , Spectrophotometric determination of food dyes in soft drinks by second order multivariate calibration of the absorbance spectra-PH data matrices , 97,Dyes Pigments , 330-339 , 2013.

N. Pourreza and M. Ghomi , Simultaneous cloud point extraction and spectrophotometric determination of carmoisine and brilliant blue FCF in food samples , 84, Talanta , 2011,240.

H. Rouhollah , H. Mohammed , A. Mohammed and Z. Sanaz , A Simple method for simultaneous spectrophotometric determination of brilliant blue FCF and sunset yellow in food samples after cloud point extraction , 38(03), J. Chem. Soc. Pak. , 2016,438- 445.

D. Nilesh , P. Arpan and B. Pratar , An efficient cloud point extraction method for the separation of congo red using triton-100 in the presence additives , 54A, I. J. Chem. , 2015,627-632

Y. Wang , Z. Zhang , Y. Xiao and N. Li , Spectrophotometric determination of sunset yellow in beverage after preconcentration by the cloud point extraction method , Analytical methods , Received 28th june 2014 , Accepted 26th September2014,DOI:10.1039/c4ay 01537a .

N. Pourreza and S. Elhami, Cloud point extraction and spectrophotometric determination of Amaranth in food samples using nonionic surfactant Triton-100 and Tetrabutylammonium Hydrogen Sulfate, 6(4), J. Iran. Chem. Soc., 2009,784-788

A. T. Bisgin, Y. Surme, M. Ucan and I. Narin, Solid-phase extraction and spectropho-tometric determination of Allura red (E129) in foodstuff,soft drink,syrup and energy drink samples:a comparison study, Int. J. Food Sci. Tech., ,2016,1-9.

M. Soylak, Y.E. Unsal and M. Tuzen, Spectrophotometric determination of trace levels of Allura red in water samples after sepration and preconcentration, 49, Food and Chemical Toxicology, 2011,1183-1187

M. Soylak, Y.E. Unsal and M. Tuzen, Spectrophotometric determination of trace levels of Allura red in water samples after sepration and preconcentration, 49, Food and Chemical Toxicology, 2011,1183-1187.

A. T. Bisgin, Y. Ucan and M. Narin, Comparison of column solid-phase extraction procetures for spectrophotom- etric determination of E129 (Allura red) in Foodstuff,pharmceutical, and energy drink samples, 98, J. AOAC Int., 2015,946-952.

N. Yoshioka and K. Ichihasshi, Determina-tion of 40 synthetic food colors in column with photodiode array detection, 74, Talanta, 2008,1408-1413.




DOI: http://dx.doi.org/10.23851/mjs.v28i3.157

Refbacks

  • There are currently no refbacks.


Copyright (c) 2018 Al-Mustansiriyah Journal of Science

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.


Copyright (c) 2018 by Al-Mustansiriyah Journal of Science
ISSN: 1814-635X (Print), ISSN: 2521-3520 (online)